[Spike recognises her as distinctly not human (yay creepy noses!) but vampire isn't what springs to mind since they don't smell like Buffyverse vampires exactly. I think. I'm making this up as I go along here, I don't know much about Twilight. Anyway, he doesn't let on that he knows she's not human. Not right away, anyway, though he does touch his pocket to make sure the stake's still there. Instead, he approaches her calmly.]
Bit late for a stroll, isn't it? You should be careful.
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Bit late for a stroll, isn't it? You should be careful.